杂质离子对高温下C11A7·CaF2的形成与稳定性的影响

下载:

PDF (8815KB)
输出: BibTeX | EndNote (RIS)

摘要本文主要研究了Fe₂O₃、MgO、BaO和ZnO等杂质离子对C₁₁A₇·CaF₂的形成和稳定性的影响。结果表明：杂质离子对C₁₁A₇·CaF₂的形成和稳定性的影响视杂质离子的种类和其掺量而异。铁或镁的氧化物的掺入，使得C₁₁A₇·CaF₂熔融温度降低，产物中C₁₁A₇·CaF₂生成量减少；掺入氧化钡后，由于钡会与样品中铝组分化合形成BaAl₂O₄，因而也使得C₁₁A₇·CaF₂生成量减少；氧化锌可以有效地促进样品中CaO的吸收，且不影响C₁₁A₇·CaF₂的最终生成数量，氧化锌除可少量固溶于C₁₁A₇·CaF₂中外，其余大部分则是以游离ZnO（红锌矿）形式存在。

	服务
	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	（）
	作者相关文章
	范庆新
	余其俊
	韦江雄

关键词: C₁₁A₇·CaF₂ 杂质离子形成稳定性

Abstract: The effect of doped ions on the formation and stability of C₁₁A₇·CaF₂ at high temperature was investigated. The results show that the effect of doped ions on the formation and stability of C11A7·CaF2 is depended on the kind and amount of doped ions. The melting point and formed amount of C₁₁A₇·CaF₂ is decreased when Fe₂O₃ or MgO is doped. With the addition of BaO the formed amount of C₁₁A₇·CaF₂ is also reduced due to the decrease of aluminum content available for the formation of C₁₁A₇·CaF₂ due to the reaction between BaO and aluminum oxide. The addition of ZnO can effectively promote the decrease of free CaO content in the reaction system and has no visible influence on the formed amount of C₁₁A₇·CaF₂. Most of doped ZnO exist in the form of free ZnO only with a little being combined with C₁₁A₇·CaF₂ to form solid solution.

Key words: C₁₁A₇·CaF₂ Doped ions Formation Stability

收稿日期: 2006-12-12 出版日期: 2007-05-25 发布日期: 2018-07-11 整期出版日期: 2007-05-25

TQ172.18

引用本文:

范庆新, 余其俊, 韦江雄.

杂质离子对高温下C₁₁A₇·CaF₂的形成与稳定性的影响

[J]. 水泥技术, 2007, 1(3): 26-30.
FAN Qing－xin, YU Qi－jun , WEI Jiang－xiong . The Effect of Doped Ions on the Formation and Stability of C11A7·CaF2 at High Temperature. Cement Technology, 2007, 1(3): 26-30.

链接本文:

http://www.cemteck.com/CN/ 或 http://www.cemteck.com/CN/Y2007/V1/I3/26

[1]	. Review and Prospect of Engineering Practice of Waste Disposal in Cement Kiln in China[J]. Cement Technology, 2018, 1(1): 17 -21 .
[2]	DI Dongren, TAO Congxi, CHAI Xingteng. Revision of Cement Energy Consumption Standards and Energy Saving Technology(Ⅰ)[J]. Cement Technology, 2018, 1(1): 22 -26 .
[3]	LIU Yonggang, GAO Hongwei, XIAO Guiqing. Design Method of Road Structure Using Lean Concrete Base[J]. Cement Technology, 2018, 1(1): 27 -31 .
[4]	LIU Xu, LI Liang. Investigation of New Medium Temperature Wear-resistant Alloy Steel[J]. Cement Technology, 2018, 1(1): 32 -34 .
[5]	MA Debao. Finite Element Analysis of Inverted Cone in Raw Meal Silo[J]. Cement Technology, 2018, 1(1): 35 -38 .
[6]	HAN Zhongqi. [J]. Cement Technology, 2018, 1(1): 38 -48 .
[7]	XIE Jianzhong, LIAN Xuewen. Analysis and Solution of Segregation of the Kiln Ash in Continuous Raw Meal Homogenization Silo#br#[J]. Cement Technology, 2018, 1(1): 49 -53 .
[8]	WEI Can, ZHANG Yuanyuan, AI Jun. Application of Cement Intelligent Control System in Overseas Projects[J]. Cement Technology, 2018, 1(1): 60 -64 .
[9]	JIN Shuang. [J]. Cement Technology, 2018, 1(1): 72 -73 .
[10]	ZHANG Jiangtao, LIU Baoliang. Processing of the Wet Materials of the Winter Cement Factory in the High Cold Region[J]. Cement Technology, 2018, 1(1): 74 -82 .