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水泥技术, 2025, 1(3): 2-10    doi: 10.19698/j.cnki.1001-6171.20253002
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浅谈碳酸盐分解耦合CO2原位还原技术国内外研究进展
中国建材装备集团有限公司天津水泥工业设计研究院有限公司,天津  300133;
The Research Progress of Carbonate Decomposition Coupled with CO2 In-situ Reduction Technology at Home and Abroad
 CNBM Equipment Group, Tianjin Cement Industry Design & Research Institute Co., Ltd. , Tianjin 300133, China 
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摘要 探讨了甲烷干重整(CH4-DRM)与碳酸盐分解技术协同应用于水泥行业CO2减排的潜力及工业应用前景。介绍了CH4-DRM反应的基本原理及热力学特性,分析了其在CO2资源化利用中的关键作用,并总结了相关催化剂设计和反应条件优化的研究进展。对于碳酸盐分解的原位CO2还原,探讨了其热效率优势及与CH4-DRM的工业耦合路径,评估了工业化应用的可行性。最后,从明晰反应机理、工艺整合、催化剂优化和规模化利用评估等方面提出了未来研究方向,为水泥行业低碳转型提供理论支持和技术指导。
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赵琳
赵亮
王佳硕
杨欢迎
关键词:  碳酸盐分解  耦合  CH4干重整  Ni基催化剂  CO2减排  CO2资源化利用    
Abstract: This paper discusses the potential of synergistic application of methane dry reforming (CH4-DRM) and carbonate decomposition technology for CO2 emission reduction in the cement industry and its industrial application prospects. The basic principle and thermodynamic characteristics of CH4-DRM reaction are introduced, and its key role in CO2 resource utilization is analyzed. The research progress of related catalyst design and reaction condition optimization is also summarized. For in-situ CO2 reduction via carbonate decomposition, the thermal efficiency advantages and the industrial coupling approaches with CH4-DRM are discussed, and the feasibility of industrial application is evaluated. Finally, the future research directions are proposed based on clarifying reaction mechanism, process integration, catalyst optimization and large-scale utilization evaluation, providing theoretical support and technical guidance for the low-carbon transformation of the cement industry.
Key words:  carbonate decomposition    coupling    CH4 dry reforming    Ni-based catalyst    CO2 emission reduction    CO2 resource utilization
收稿日期:  2025-02-19                出版日期:  2025-05-25      发布日期:  2025-05-25      整期出版日期:  2025-05-25
ZTFLH:  X701.7  
基金资助: 国家重点研发计划项目(2022YFA1504700)
作者简介:  赵 琳(1989—),女,博士,高级工程师,主要从事大气污染物净化技术及材料的研究。E-mail:zhaolin3@sinoma-tianjin.cn
引用本文:    
赵琳, 赵亮, 王佳硕, 杨欢迎. 浅谈碳酸盐分解耦合CO2原位还原技术国内外研究进展[J]. 水泥技术, 2025, 1(3): 2-10.
ZHAO Lin, ZHAO Liang, WANG Jiashuo, YANG Huanying. The Research Progress of Carbonate Decomposition Coupled with CO2 In-situ Reduction Technology at Home and Abroad. Cement Technology, 2025, 1(3): 2-10.
链接本文:  
http://www.cemteck.com/CN/10.19698/j.cnki.1001-6171.20253002  或          http://www.cemteck.com/CN/Y2025/V1/I3/2
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