摘要 甲烷干重整(Dry Reforming of Methane,DRM)技术是CO2资源化利用的技术之一,Ni基催化剂的应用可以降低DRM反应的能量。分析了DRM反应过程中Ni基催化剂的反应机理,以及Ni基催化剂表面积碳、金属活性组分烧结、硫中毒等导致Ni基催化剂失活的原因。综述了当前提高Ni基催化剂催化性能的研究成果,展望了未来开发具有高稳定性、高选择性、高活性和高抗积碳性能的Ni基催化剂的研究方向,为Ni基催化剂在DRM反应中的工业化应用提供了理论指导和研究依据。
Abstract: Dry Reforming of Methane (DRM) technology is one of the technologies for CO2 resource utilization, the application of Ni-based catalyst can reduce the energy of DRM reaction. The research analyzes the reaction mechanism of Ni-based catalysts during the DRM reaction process, as well as the cause of the reasons for the loss of Ni-based catalysts such as carbon, metal activated component sintering, sulfur poisoning, etc. This paper describes the research results of currently improving the catalytic performance of Ni-based catalysts, and provides a research direction for the future development of Ni-based catalysts with high stability, selectivity, activity, and resistance to carbon deposition. And it provides theoretical guidance and research basis for the industrial application of Ni-based catalyst in DRM.