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水泥技术, 2025, 1(3): 71-77    doi: 10.19698/j.cnki.1001-6171.20253071
  实验研究 本期目录 | 过刊浏览 | 高级检索 |
煤矸石活化方法实验研究
1 中建八局第二建设有限公司,山东  济南  250000;  2 山东山水水泥集团有限公司,山东  济南  250000
Experimental Study on Activation Method of Coal Gangue
1 China Construction Eighth Engineering Division Second Construction Co., Ltd. , Jinan Shandong 250000, China;
2 Shandong Shanshui Cement Group Co., Ltd. , Jinan Shandong 250000, China
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摘要 煤矸石含有一定比例的高岭石,可用作水泥混合材,但其火山灰活性极低,利用率较低。为了提高煤矸石利用率,通过元素分析、物相分析和TG-DSC热分析,对比了不同产地的煤矸石和高岭土的碱含量、高岭石含量、放热焓值;研究了煅烧温度、粉磨细度、高岭石含量等对煤矸石火山灰活性的影响。结果表明,煅烧温度约1 000℃时,煤矸石放热焓与高岭石含量线性正相关;不同的煅烧温度,不同产地的煤矸石3d、14d火山灰效应强度贡献率影响不同;粉磨细度对煤矸石3d、14d火山灰活性有显著影响;煤矸石中的铁元素含量越高,煅烧后的煤矸石越红,越影响其在水泥中的应用。在工业生产时,应通过热分析定性预测煤矸石火山灰活性,通过实验确定最佳煅烧温度和粉磨细度,检测判断煤矸石是否存在欠烧或过烧的情况,尽量选择铁元素含量较低的煤矸石作为原料。
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马娟
杨俊博
杨柳
关键词:  煤矸石  高岭石  煅烧  火山灰效应强度  实验研究    
Abstract: Coal gangue contains a certain proportion of kaolinite and can be used as a cement admixture, but its volcanic ash activity is extremely low, leading to poor utilization.  To improve the utilization rate of coal gangue, elemental analysis, phase analysis, and TG-DSC thermal analysis were conducted to compare the alkali content, kaolinite content, and heat release enthalpy of coal gangue and kaolin from different origins. The study also investigated the effects of calcination temperature, grinding fineness, and kaolinite content on the volcanic ash activity of coal gangue.  The results show that at a calcination temperature of about 1 000℃, the heat release enthalpy of coal gangue is positively linearly related to the kaolinite content; different calcination temperatures and origins of coal gangue have varying contributions to the 3d and 14d volcanic ash effect strength; grinding fineness significantly affects the 3d and 14d volcanic ash activity of coal gangue; the higher the iron content in coal gangue, the redder the calcined coal gangue becomes, which negatively impacts its application in cement.  In industrial production, thermal analysis should be used to qualitatively predict the volcanic ash activity of coal gangue, experimental determination of the optimal calcination temperature and grinding fineness is necessary, and tests should be conducted to determine whether there are under-fired or over-fired conditions in coal gangue, with a preference for using coal gangue with lower iron content as raw material.
Key words:  coal gangue    kaolinite    calcination    volcanic ash effect strength    experimental study
收稿日期:  2024-09-04                出版日期:  2025-05-25      发布日期:  2025-05-25      整期出版日期:  2025-05-25
ZTFLH:  TQ172.44   
作者简介:  马 娟(1984—),女,本科,工程师,主要从事高性能水泥、砂浆的性能及应用研究。E-mail:mj907@163.com
引用本文:    
马娟, 杨俊博, 杨柳. 煤矸石活化方法实验研究[J]. 水泥技术, 2025, 1(3): 71-77.
MA Juan, YANG Junbo, YANG Liu. Experimental Study on Activation Method of Coal Gangue. Cement Technology, 2025, 1(3): 71-77.
链接本文:  
http://www.cemteck.com/CN/10.19698/j.cnki.1001-6171.20253071  或          http://www.cemteck.com/CN/Y2025/V1/I3/71
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