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Research Progress of CO-SCR Denitration Catalyst at Home and Abroad
ZHAO Lin, HAN Hui, DU Liangbo, YANG Huanying, PENG Xueping
Cement Technology    2023, 1 (4): 19-27.   DOI: 10.19698/j.cnki.1001-6171.20234019
Abstract   PDF (6497KB)  
 At present, developing low temperature, high activity, high stability and low cost catalysts is the key research direction of CO-SCR technology. This paper mainly introduces the catalytic reduction mechanism of CO-SCR technology, and reviews the research progress of CO-SCR catalysts at home and abroad in recent years, starting with noble metal catalysts and transition metal oxides catalysts. Numerous studies have shown that CO-SCR catalysts still have many limitations. To achieve large-scale industrial applications, further theoretical calculations need to be combined to improve the antioxidant performance of the catalyst, and the detailed influence paths of factors such as H2O, SO2, and alkali metals in CO-SCR reactions need to be analyzed.
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Development Status and Trend of Hydrogen Energy in Cement Industry under Background  of Carbon Peaking and Carbon Neutrality
LI Huajun, YANG Huanying, MA Jiaomei, ZHAO Liang, WANG Jiashuo
Cement Technology    2023, 1 (3): 15-24.   DOI: 10.19698/j.cnki.1001-6171.20233015
Abstract   PDF (4611KB)  
Hydrogen energy has the characteristics of clean and pollution-free, high energy density per unit mass, etc., and is regarded as one of the most promising clean energy in the 21st century. Its application in cement, thermal power, automobile and other fields has become the focus of technical research in various countries. The development status of hydrogen energy in cement industry at home and abroad is mainly the direct combustion of hydrogen as fuel to generate energy and the combined use of hydrogen and carbon utilization technology (CCUS). The key of hydrogen direct combustion technology is to increase the substitution rate of alternative fuels to fossil fuels by adding hydrogen. The key to the combined use of hydrogen and CCUS lies in the capture of CO2 and the development of high efficiency catalyst for the hydrogenation of CO2 to methanol. Combined with the existing spontaneous combustion, early combustion, tempering, NOX emissions of hydrogen energy combustion in the hydrogen internal combustion engine, gas turbines and other industrial fields, the current development situation and future trend of hydrogen energy in our cement industry are analyzed.
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Development Status and Optimization Approach of Intelligent Cement Grinding System
SHI Guoping, LIU Dongqiang
Cement Technology    2023, 1 (5): 13-17.   DOI: 10.19698/j.cnki.1001-6171.20235013
Abstract   PDF (4187KB)  
Cement grinding system is currently in the stage of transformation from automation to intelligence in China. Many intelligent technologies have been applied in the aspects of system intelligent operation, product quality monitoring, equipment maintenance, on-site monitoring and management, etc., however, there is still a distance from the full process intelligence of the cement grinding system. Aiming at the intelligent realization path of cement grinding system, the idea of transforming from intelligent operation mode to smart operation mode is proposed, and through the realization of digital management of the whole life cycle from design to operation and maintenance, intelligent regulation of grinding production and operation process, a composite intelligent operation control system and equipment dynamic management system based on neural network multi-variable model are established. In combination with intelligent production modes such as adjusting particle size distribution and classification respectively grinding system etc., it will work together from both software and hardware to achieve the intelligence of the cement grinding system in the smart operation mode of the whole process in multiple ways.
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Research Progress of Magnesium Phosphate Cement
LIU Ruinan, WANG Liyan
Cement Technology    2023, 1 (3): 87-90.   DOI: 10.19698/j.cnki.1001-6171.20233087
Abstract   PDF (2814KB)  
Magnesium phosphate cement has a short setting time and high early strength, and has broad prospects in civil buildings such as airport runways, tunnels, mines, and emergency repairs of national defense projects. However, magnesium phosphate cement hydrates very quickly and has a very short setting time, resulting in the inability to carry out engineering construction. This article summarizes the new achievements in the influence of factors such as raw materials, retarders, and admixtures on the setting time of magnesium phosphate cement at present, as well as new measures to improve the compactness, adhesion, and frost resistance of magnesium phosphate cement. It also looks forward to the development prospects of magnesium phosphate cement.
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Impact of the Clearance between Kiln Tyre and Backing Plate on Production and its Adjustment Measure

WANG Jianqiang, NIU Hai, CHEN Hao
Cement Technology    2023, 1 (6): 72-75.   DOI: 10.19698/j.cnki.1001-6171.20236072
Abstract   PDF (3077KB)  

Based on the operation data of ?4.8m×74m rotary kiln, it briefly descrbes the measuring method of the clearance between the kiln tyre and the backing plate by measuring the thermal expansion and slippage, and the impact of clearance size on the operation of rotary kiln and its adjustment measures. Excessive clearance between the kiln tyre and the backing plate would easily cause the breakage and fall-off of the refractory bricks and shorten its service life, while too small clearance would easily cause uneven thermal expansion of the rotary kiln and result in the "necking" phenomenon, which would seriously affect the safe operation of the kiln. By strengthening the lubrication and maintenance, adjusting the thickness of the backing plate, replacing the backing plate, etc., the clearance between the kiln tyre and the backing plate could be ensured within a reasonable range, which reduce costs of kiln maintenance, and further improve the operation rate of the rotary kiln.

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Application of On-line Monitoring and Intelligent Controlling System for Grate Cooler
CONG Xiaojing, XU Longxu, CONG Jiaqing, YOU Xiaoping
Cement Technology    2023, 1 (2): 37-.   DOI: 10.19698/j.cnki.1001-6171.20232037
Abstract   PDF (9181KB)  
Through the application of digital intelligent control technology, the on-line monitoring of grate cooler layer thickness, automatic adjustment of grate bed travel and speed, iterative optimization of multi-variable intelligent control module, intelligent control of clinker moving speed, cooling air volume and air pressure, intelligent maintenance of grate cooler is realized, which improves the reliability of grate cooler operation and reduces the maintenance cost. The clinker production quality is stabilized and the management level of cement production enterprises is improved.

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Energy Conversation and Carbon Reduction for 10 000t/d Clinker Pyro System
MA Jiaomei, WANG Kedong, SUI Mingjie, GAO Weimin
Cement Technology    2023, 1 (1): 15-23.   DOI: 10.19698/j.cnki.1001-6171.20231015
Abstract   PDF (6543KB)  
Aiming at the technical bottleneck of energy efficiency improvement of CUCC(Xuzhou)
10 000t/d production line Ⅰ, a solution of pollution reduction and carbon reduction of pyro system was proposed. The five-stage preheater was changed to six-stage preheater for the first time in chinese cement industry. The calciner volume was expanded and self-denitrification technology was adopted to improve the efficiency of the main combustion area, the speed of rotary kiln was accelerated, and the cooler was changed to the fourth-generation cooler with middle roll crusher. After the transformation, the outlet temperature of the preheater is reduced by 83℃, the standard coal consumption of clinker is reduced by about 14kg/t.cl, the comprehensive coal consumption per unit product of clinker reaches and is lower than the level 1 index of GB 16780-2021 standard by about 4%, 43 000 tons of standard coal is saved every year, and the annual carbon dioxide emission is reduced by 108 000 tons. Meanwhile, the emission reduction technology of self-denitrification source is applied in the existing preheater tower. The NOX emission is lower than 25mg/Nm3 required by the local environmental protection department, the ammonia consumption is reduced by 10 000 tons, and provide a technology demonstration for the new upgrading of cement manufacturing under the double carbon strategy background, double control of energy consumption and ultra-low emission targets.
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Research and Application on Improving Energy Efficiency of Cement Clinker Pyro-system
MA Jiaomei, ZHAO Liang, ZHANG Jianguo, WANG Kexue
Cement Technology    2023, 1 (2): 20-.   DOI: 10.19698/j.cnki.1001-6171.20232020
Abstract   PDF (3298KB)  
Based on the requirements of double control of energy consumption in the cement industry under the background of double carbon, the main factors affecting heat consumption in the thermal balance expenditure of the existing production line were analyzed through the calculation of thermal efficiency. It put forward the energy efficiency improvement solution, which is typically applied in the technical transformation of the existing production line, and the thermal efficiency of the sintering system is further increased by 5%~9%. Fuel consumption per unit product of clinker can be reduced by more than 10kg/t.cl, reaching and better than level 1 of GB 16780-2021. It improves energy efficiency while taking into account the environmental protection function of the pyro-system, through the application of calciner self-denitrification technology to reduce source emission. The CO content out of calciner would not exceed 500ppm and the original NOx before ammonia below 350mg/Nm3, the ammonia water consumption below 3kg/t.cl under the condition of NOx emission below 50mg/Nm3 of environmental protection requirements. These measures and technology would help the plants to meet the rapid development of enterprises.
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Research Progress and Engineering Demonstration of CCUS Technology
JIN Zhouzheng, PENG Xueping, CHEN Changhua, DAI Zhongyuan, ZHANG Donghui
Cement Technology    2025, 1 (1): 2-8.   DOI: 10.19698/j.cnki.1001-6171.20251002
Abstract   PDF (6659KB)  
This paper systematically analyzes the research progress of typical CCUS technologies worldwide, including oxy-fuel combustion, chilled ammonia absorption, membrane separation, calcium looping technologies, etc. It focuses on the research outcomes of the Qingzhou Zhonglian oxy-fuel combustion coupled carbon capture demonstration project. The Qingzhou Zhonglian demonstration project achieved efficient carbon capture in cement production through full oxy-fuel combustion technology, overcoming key technical challenges such as high-oxygen concentration flame control, CO2 enrichment concentration, and meal calcining rate under high CO2 concentration conditions, through innovative methods such as graded oxygen supply and discrete dilution combustion, the energy consumption and cost of carbon capture have been significantly reduced. The research indicates that oxy-fuel combustion technology can increase the CO2 concentration in flue gas to over 80%, laying a foundation for low-energy physical carbon capture. The successful operation of the Qingzhou Zhonglian demonstration project provides an important example for the industrial application of low-carbon technologies in the cement industry.
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Optimization and Modification of Ball Mill System
CHEN Yifang, GU Deming, ZHANG Xiangyang
Cement Technology    2023, 1 (1): 35-42.   DOI: 10.19698/j.cnki.1001-6171.20231035
Abstract   PDF (5189KB)  
With the development of the roller press combined grinding system, the internal structure of the ball mill suitable for this system should be optimized. With the optimization and modification of the feeding device, the liners structure, the intermediate diaphragm, the dam ring, and the heat-proof material, the operation efficiency of the ball mill is effectively improved and the energy consumption of the ball mill is reduced.
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